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Chemical Principles II |
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Chapter 16: 22a, 30, 32, 35 (Rate = k[A][B]2, 50.0 L2/mol2 s), 41, 43 Chapter 17: 3, 6 (no), 20, 31, 37 (to the left), 47, 51, 54 (0.0249), 64 (no change, no change, toward the products, toward the reactants), 67, 72 (decrease, decrease, decrease, increase), 75 (low P, high T), 89, 94 (360), 106 (422, 20.5 M) Chapter 12: 20 (-2.04 x 10(4) J), 37, 40ab (dispersion, dipole-dipole interactions), 50 (CH3CH2OH, NO, H2Te), 51bc, 87ab (molecular, ionic), 89bc (ionic, molecular) Chapter 13: 14b (dipole-dipole interactions can form), 39 (increase, stay same), 58, 86, 92, 95 (5.1 degC), 96 Chapter 18: 4, 11, 23, 25, 29, 44 (PO43-, NH3, S2-), 46 (OH-, HSO4-, H3O+), 63, 65, 71, 75a, 86, 90, 92, 98, 100, 107, 110ac, 120c (basic), 121ab, 124b (basic), 142 Chapter 19: 2, 13, 15, 19, 23, 35, 58a, 63, 70, 72, 74, 76, 84a, 144 (1.88, 57.11 mL, 5.22, 8.08, 10.92) Chapter 20: 6, 16, 44, 50, 52, 58, 63, 74, 81 (1.0 x 10(-5) M), 82 (deltaHo = -1.896 kJ/mol, deltaSo = 3.247 J/molK, deltaGo = -2864 kJ/mol; deltaGo is positive at all temperatures for the conversion of graphite to diamond), 91 (-29.2 kJ, favored at low T, -182 kJ) Chapter 21: 48, 58, 62, 70abc, 105, 109, 130
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